Water quality of boiler blowdown?

QUESTION:

We're trying to determine what types of contaminants may have been encountered in boiler blowdown from a steam-driven power generating plant built in 1909 in Oakland, CA. We suspect heavy metals leached from the steel tanks and condenser equipment. Does anybody know which metals specifically and in what concentrations (typically)?
Anything other than metals? We have observed relatively high pH levels
(9 to 10) in modern blowdown.

ANSWER:

There is possibly Ni and Cr in the boiler tube steel. Most likely, there is nothing of consequence in any of the rest of the steel components in contact with boiler water and steam. (Other than iron!!) The condenser is probably made of bronze (Cu + Sn)
The mere fact that the plant has been around since 1909 suggests that there was not significant leaching of metallic components.


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